Hi, nice pump you found, I really like that price.
The drivers you mentioned in the email, DRV8825 or A4988, would be ok. I think it might be easiest to first find a tutorial with some basic code to run on the Pi so you can get things working. Then move over to reef-pi for control but I don't know if it's possible.
Hopefully you have a DB9 serial connector available on the main controller, these are all untouched GPIO's from the Pi. In the tutorial it should show connections directly to the Pi GPIO's so on controller just connect to the DB9. You can get a DB9 adapter to make connections easier.
The latest reef-pi does have support for stepper drivers but I haven't heard of anyone using it so don't know if or how well it works. I am thinking it might not work for your application as I believe reef-pi only controls them as a dosing pump which I don't think you could configure for an ATO. If you have the latest reef-pi running see if you can access it from ATO tab but I think only on dosing pump tab. It will also require 5 or 6 GPIO's so you'll only be able to connect one unless a bunch of them can share a GPIO in reef-pi. When you look at the settings you'll see what the GPIO's are for.
Another option is to run a script for the stepper motors and use the reef-pi API to interact with the script but that would be fairly advanced.